XPS Analysis of Zinc Injection Effects on Oxide Film of 316 L Stainless Steel

Abstract

Abstract:

In this paper, the Zn-addition experiments with concentrations of 10 μg/L, 60 μg/L and 120 μg/L respectively were reported on 316 L stainless steels (SSs) in flowing simulated PWR water. The structures of surface oxide films were analyzed by X-ray photoelectron spectroscopy (XPS). The results show that the corrosion rate of 316 L SSs could be significantly reduced by adding Zn2+, and in the concentration range of 10 μg/L to 60 μg/L, the corrosion weight gain decreases as Zn concentration increases; it is also indicated that Zn2+ is likely to replace Fe2+ and Ni2+ in FeNi spinel, thus forming a stable ZnCr2O4.

Key words：

Key words: 316 L stainless steels, Zn-addition, oxide films, X-ray photoelectron spectroscopy (XPS)

CLC Number:

TG 172.82

Cite this article

PAN Xiangfeng1,DUAN Zhengang1,ZHANG Lefu1,WANG Li1, XU Xuelian2,SHI Xiuqiang2. XPS Analysis of Zinc Injection Effects on Oxide Film of 316 L Stainless Steel[J]. Journal of Shanghai Jiaotong University, 2014, 48(03): 417-421.

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References

［1］Lister D H, Godin M S. The effect of dissolved zinc on the transport of corrosion products in PWRs［R］. NP6975D, Palo Alto: EPRI, 1990.72.

［2］Roumiguière F. Field experience on Zn injection on PWR plants with a view to dose rate reduction［C］∥International Conference of Nuclear Energy for New Europe 2005. Bled, Slovenia: ［s.n.］, 2005.

［3］Stellwag B. The mechanism of oxide film formation on austenitic stainless steels in high temperature water ［J］. Corrosion Science, 1998, 40(2/3): 337370.

［4］Huang J, Liu X, Han E, et al. Influence of Zn on oxide films on alloy 690 in borated and lithiated high temperature water ［J］. Corrosion Science, 2011, 53:32543261.

［5］Machet A, Galtayries A, Marcus P, et al. XPS study of oxides formed on nickelbase alloys in hightemperature and highpressure water ［J］. Surf Interface Anal, 2002, 34(l): 197200.

［6］Beverskog B. The role of zinc in LWRs ［C］∥Int Conf on Water Chemistry of Nuclear Reactor Systems. San Francisco: IFE, 2004: 26.

［7］刘侠和, 吴欣强, 韩恩厚. 轻水堆结构材料在加锌水中的腐蚀行为研究现状与进展［J］. 腐蚀科学与防护技术, 2011, 23(4): 287292.

LIU Xiahe, WU xinqiang, HAN Enhou. Status and progress on study of corrosion behavior of structural materials in Zninjected waters for LWRs ［J］. Corrosion Science and Protection Technology, 2011, 23(4): 287292.

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