Synthesis and Applications of Porous Glass

doi:10.1007/s12204-019-2131-1

Abstract

Abstract: Porous materials have received significant attention for catalyst, electrochemical energy storage, sensing and compound capture. Large surface area and connected inner channel make porous materials outstanding in the applications of catalyst, batteries and biomedicine. Glass is a traditional material and has the advantages of high stability and other physical properties. By combining the advantages of porous materials and glass, porous glass has been researched widely and applied to many leading-edge fields, such as batteries and sensors. This review presents common methods for synthesizing porous glass, including phase separation process (PSP), direct leaching process (DLP) of acid, sintering and so on. Three main steps for fabrication of each process are concluded. The recent applications are support, capturer and matter transport, and they are highlighted in this review. Future directions for preparing these materials are also discussed.

Key words: porous glass| ordered structure| hierarchical structure

摘要： Porous materials have received significant attention for catalyst, electrochemical energy storage, sensing and compound capture. Large surface area and connected inner channel make porous materials outstanding in the applications of catalyst, batteries and biomedicine. Glass is a traditional material and has the advantages of high stability and other physical properties. By combining the advantages of porous materials and glass, porous glass has been researched widely and applied to many leading-edge fields, such as batteries and sensors. This review presents common methods for synthesizing porous glass, including phase separation process (PSP), direct leaching process (DLP) of acid, sintering and so on. Three main steps for fabrication of each process are concluded. The recent applications are support, capturer and matter transport, and they are highlighted in this review. Future directions for preparing these materials are also discussed.

关键词: porous glass| ordered structure| hierarchical structure

CLC Number:

TQ 127.2

ZHU Benbi (朱本必), ZHANG Zhijian (张志坚), ZHANG Wang (张旺), WU Yu (吴昱), ZHANG Jianzhong (章建忠), IMRAN Zada, ZHANG Di (张荻). Synthesis and Applications of Porous Glass[J]. Journal of Shanghai Jiao Tong University (Science), 2019, 24(6): 681-698.

References 126

[2]	TOLDRA F, JANSEN N B, TSAO G T. Use of porous glass fiber as a support for biocatalyst immobilization[J]. Biotechnology Letters, 1986, 8(11):785-790.
[3]	NORDBERG M E. Properties of some vycor-brandglasses [J]. Journal of the American Ceramic Society,1944, 27(10): 299-305.
[1]	ENKE D, OTTO K, JANOWSKI F, et al. Twophase porous silica: Mesopores inside controlled pore glasses [J]. Journal of Materials Science, 2001, 36(9):2349-2357.
[4]	JANOWSKI F, ENKE D. Porous glasses[C]//Handbook of Porous Solids. Weinheim: Wiley-VCH Press, 2002: 1432-1542.
[2]	TOLDRA F, JANSEN N B, TSAO G T. Use of porous glass fiber as a support for biocatalyst immobilization[J]. Biotechnology Letters, 1986, 8(11):785-790.
[5]	SIEBERS F, GREULICH N, KIEFER W. Manufacture,properties and application of open-pore sinteredglasses and open-pore sintered glass-ceramics[J]. Glastechnische Berichte, 1989, 62(2): 63-73.
[3]	NORDBERG M E. Properties of some vycor-brandglasses [J]. Journal of the American Ceramic Society,1944, 27(10): 299-305.
[6]	UNGER K K. Porous silica: Its properties and useas a support in column liquid chromatography [J].Journal of Chromatography Library, 1979, 16: 336.
[7]	ENKE D, JANOWSKI F, SCHWIEGER W. Porousglasses in the 21st century: A short review [J]. Microporousand Mesoporous Materials, 2003, 60(1): 19-30.
[4]	JANOWSKI F, ENKE D. Porous glasses[C]//Handbook of Porous Solids. Weinheim: Wiley-VCH Press, 2002: 1432-1542.
[8]	ELMER T H. Leaching of E-glass [J]. Journal of theAmerican Ceramic Society, 1984, 67(12): 778-782.
[5]	SIEBERS F, GREULICH N, KIEFER W. Manufacture,properties and application of open-pore sinteredglasses and open-pore sintered glass-ceramics[J]. Glastechnische Berichte, 1989, 62(2): 63-73.
[9]	SIMONOVA L G, PAUKSHTIS E A, DOVLITOVA L S, et al. Study of leaching of sodium aluminosilicatefiberglass materials [J]. Russian Journal of InorganicChemistry, 2015, 60(9): 1052-1058.
[6]	UNGER K K. Porous silica: Its properties and useas a support in column liquid chromatography [J].Journal of Chromatography Library, 1979, 16: 336.
[10]	REINHARDT B, HERWIG J, RANNABAUER S, etal. Hierarchically structured glass monoliths based onpolyurethane foams as template [J]. Journal of theEuropean Ceramic Society, 2014, 34(5): 1465-1470.
[11]	VELEV O D, JEDE T A, LOBO R F, et al. Poroussilica via colloidal crystallization [J]. Nature, 1997,389(6650): 447-448.
[7]	ENKE D, JANOWSKI F, SCHWIEGER W. Porousglasses in the 21st century: A short review [J]. Microporousand Mesoporous Materials, 2003, 60(1): 19-30.
[8]	ELMER T H. Leaching of E-glass [J]. Journal of theAmerican Ceramic Society, 1984, 67(12): 778-782.
[12]	INAYAT A, REINHARDT B, UHLIG H, et al. Silicamonoliths with hierarchical porosity obtained fromporous glasses [J]. Chemical Society Reviews, 2013,42(9): 3753-3764.
[9]	SIMONOVA L G, PAUKSHTIS E A, DOVLITOVA L S, et al. Study of leaching of sodium aluminosilicatefiberglass materials [J]. Russian Journal of InorganicChemistry, 2015, 60(9): 1052-1058.
[13]	KAMEGAWA T, ISHIGURO Y, SETO H, et al.Enhanced photocatalytic properties of TiO2-loadedporous silica with hierarchical macroporous andmesoporous architectures in water purification [J].Journal of Materials Chemistry A, 2015, 3(5): 2323-2330.
[10]	REINHARDT B, HERWIG J, RANNABAUER S, etal. Hierarchically structured glass monoliths based onpolyurethane foams as template [J]. Journal of theEuropean Ceramic Society, 2014, 34(5): 1465-1470.
[14]	KUANG D, BREZESINSKI T, SMARSLY B. Hierarchicalporous silica materials with a trimodal poresystem using surfactant templates [J]. Journal of theAmerican Chemical Society, 2004, 126(34): 10534-10535.
[11]	VELEV O D, JEDE T A, LOBO R F, et al. Poroussilica via colloidal crystallization [J]. Nature, 1997,389(6650): 447-448.
[15]	XIONG J, ZHU W S, DING W J, et al. Controllablesynthesis of functionalized ordered mesoporoussilica by metal-based ionic liquids, and their effectiveadsorption of dibenzothiophene [J]. RSC Advances,2014, 4(76): 40588-40594.
[16]	INAYAT A, REINHARDT B, HERWIG J, et al. Recentadvances in the synthesis of hierarchically poroussilica materials on the basis of porous glasses [J]. NewJournal of Chemistry, 2016, 40(5): 4095-4114.
[12]	INAYAT A, REINHARDT B, UHLIG H, et al. Silicamonoliths with hierarchical porosity obtained fromporous glasses [J]. Chemical Society Reviews, 2013,42(9): 3753-3764.
[17]	IZUMI K, UTIYAMA M, MARUO Y Y. ColorimetricNOx sensor based on a porous glass-based NO2 sensingchip and a permanganate oxidizer [J]. Sensors andActuators B: Chemical, 2015, 216: 128-133.
[13]	KAMEGAWA T, ISHIGURO Y, SETO H, et al.Enhanced photocatalytic properties of TiO2-loadedporous silica with hierarchical macroporous andmesoporous architectures in water purification [J].Journal of Materials Chemistry A, 2015, 3(5): 2323-2330.
[18]	FANG X E, WEI S S, KONG J L. Paper-based microfluidicswith high resolution, cut on a glass fibermembrane for bioassays [J]. Lab on a Chip, 2014,14(5): 911-915.
[14]	KUANG D, BREZESINSKI T, SMARSLY B. Hierarchicalporous silica materials with a trimodal poresystem using surfactant templates [J]. Journal of theAmerican Chemical Society, 2004, 126(34): 10534-10535.
[19]	MAURATH J, DITTMANN J, SCHULTZ N, et al.Fabrication of highly porous glass filters using capillarysuspension processing [J]. Separation and PurificationTechnology, 2015, 149: 470-478.
[15]	XIONG J, ZHU W S, DING W J, et al. Controllablesynthesis of functionalized ordered mesoporoussilica by metal-based ionic liquids, and their effectiveadsorption of dibenzothiophene [J]. RSC Advances,2014, 4(76): 40588-40594.
[20]	GAO H C, GUO B K, SONG J, et al. A compositegel-polymer/glass-fiber electrolyte for sodium-ionbatteries [J]. Advanced Energy Materials, 2015, 5(9):1402235.
[16]	INAYAT A, REINHARDT B, HERWIG J, et al. Recentadvances in the synthesis of hierarchically poroussilica materials on the basis of porous glasses [J]. NewJournal of Chemistry, 2016, 40(5): 4095-4114.
[21]	RAHAMAN M N, DAY D E, SONNY BAL B, et al.Bioactive glass in tissue engineering [J]. Acta Biomaterialia,2011, 7(6): 2355-2373.
[17]	IZUMI K, UTIYAMA M, MARUO Y Y. ColorimetricNOx sensor based on a porous glass-based NO2 sensingchip and a permanganate oxidizer [J]. Sensors andActuators B: Chemical, 2015, 216: 128-133.
[22]	FU Q, SAIZ E, TOMSIA A P. Bioinspired strong andhighly porous glass scaffolds [J]. Advanced FunctionalMaterials, 2011, 21(6): 1058-1063.
[18]	FANG X E, WEI S S, KONG J L. Paper-based microfluidicswith high resolution, cut on a glass fibermembrane for bioassays [J]. Lab on a Chip, 2014,14(5): 911-915.
[23]	GULYAEVA Y K, KAICHEV V V, ZAIKOVSKIIV I, et al. Selective hydrogenation of acetylene overnovel Pd/fiberglass catalysts [J]. Catalysis Today,2015, 245: 139-146.
[19]	MAURATH J, DITTMANN J, SCHULTZ N, et al.Fabrication of highly porous glass filters using capillarysuspension processing [J]. Separation and PurificationTechnology, 2015, 149: 470-478.
[24]	PAUKSHTIS E A, SIMONOVA L G, ZAGORUIKOA N, et al. Oxidative destruction of chlorinated hydrocarbonson Pt-containing fiber-glass catalysts [J].Chemosphere, 2010, 79(2): 199-204.
[25]	KIWI-MINSKER L, YURANOV I, SLAVINSKAIAE, et al. Pt and Pd supported on glass fibers as effectivecombustion catalysts [J]. Catalysis Today, 2000,59(1/2): 61-68.
[20]	GAO H C, GUO B K, SONG J, et al. A compositegel-polymer/glass-fiber electrolyte for sodium-ionbatteries [J]. Advanced Energy Materials, 2015, 5(9):1402235.
[26]	HOFFMANN M, KREFT S, GEORGI G, et al. Improvedcatalytic methane combustion of Pd/CeO2catalysts via porous glass integration [J]. AppliedCatalysis B: Environmental, 2015, 179: 313-320.
[21]	RAHAMAN M N, DAY D E, SONNY BAL B, et al.Bioactive glass in tissue engineering [J]. Acta Biomaterialia,2011, 7(6): 2355-2373.
[27]	NICHOLAS D M, SHAH Y T. Carbon monoxide oxidationover a platinum-porous fiber glass supportedcatalyst [J]. Industrial & Engineering ChemistryProduct Research and Development, 1976, 15(1): 35-40.
[22]	FU Q, SAIZ E, TOMSIA A P. Bioinspired strong andhighly porous glass scaffolds [J]. Advanced FunctionalMaterials, 2011, 21(6): 1058-1063.
[28]	ENKE D, JANOWSKI F, GILLE W, et al. Structureand texture analysis of colloidal silica in porousglasses [J]. Colloids and Surfaces A: Physicochemicaland Engineering Aspects, 2001, 187/188: 131-139.
[23]	GULYAEVA Y K, KAICHEV V V, ZAIKOVSKIIV I, et al. Selective hydrogenation of acetylene overnovel Pd/fiberglass catalysts [J]. Catalysis Today,2015, 245: 139-146.
[29]	SUN Y W, WANG Y J, YANG L, et al. Heavy metalion sorption properties of porous glass beads with acore-shell structure [J]. Solvent Extraction and IonExchange, 2008, 26(5): 672-685.
[24]	PAUKSHTIS E A, SIMONOVA L G, ZAGORUIKOA N, et al. Oxidative destruction of chlorinated hydrocarbonson Pt-containing fiber-glass catalysts [J].Chemosphere, 2010, 79(2): 199-204.
[30]	IMAKITA K, KAMADA T, KAMATANI J I, et al.Room temperature direct imprinting of porous glassprepared from phase-separated glass [J]. Nanotechnology,2015, 26(25): 255304.
[25]	KIWI-MINSKER L, YURANOV I, SLAVINSKAIAE, et al. Pt and Pd supported on glass fibers as effectivecombustion catalysts [J]. Catalysis Today, 2000,59(1/2): 61-68.
[31]	NOJI T, KAWAKAMI K, SHEN J R, et al. Oxygenevolvingporous glass plates containing the photosyntheticphotosystem II pigment-protein complex [J].Langmuir, 2016, 32(31): 7796-7805.
[26]	HOFFMANN M, KREFT S, GEORGI G, et al. Improvedcatalytic methane combustion of Pd/CeO2catalysts via porous glass integration [J]. AppliedCatalysis B: Environmental, 2015, 179: 313-320.
[32]	HWANG C, KIM J, RYU B K, et al. Preparationof porous glass films using phase separation phenomenonand growth behavior of phase-separatedstructure [J]. Journal of Materials Science, 2013,48(23): 8068-8076.
[33]	BAL’ZHINIMAEV B S, SUKNEV A P, GULYAEVAY K, et al. Silicate fiberglass catalysts: From scienceto technology [J]. Catalysis in Industry, 2015, 7(4):267-274.
[27]	NICHOLAS D M, SHAH Y T. Carbon monoxide oxidationover a platinum-porous fiber glass supportedcatalyst [J]. Industrial & Engineering ChemistryProduct Research and Development, 1976, 15(1): 35-40.
[34]	REINHARDT B, ENKE D, SYROWATKA F. Preparationof porous, hierarchically organized glass monolithsvia combination of sintering and phase separation[J]. Journal of the American Ceramic Society,2012, 95(2): 461-465.
[28]	ENKE D, JANOWSKI F, GILLE W, et al. Structureand texture analysis of colloidal silica in porousglasses [J]. Colloids and Surfaces A: Physicochemicaland Engineering Aspects, 2001, 187/188: 131-139.
[35]	POOLOGASUNDARAMPILLAI G, LEE P D, LAMC, et al. Compressive strength of bioactive sol-gelglass foam scaffolds [J]. International Journal of AppliedGlass Science, 2016, 7(2): 229-237.
[29]	SUN Y W, WANG Y J, YANG L, et al. Heavy metalion sorption properties of porous glass beads with acore-shell structure [J]. Solvent Extraction and IonExchange, 2008, 26(5): 672-685.
[36]	MARANGONIM, ARNOUT L, MACHIELS L, et al.Porous, sintered glass-ceramics from inorganic polymersbased on fayalite slag [J]. Journal of the AmericanCeramic Society, 2016, 99(6): 1985-1991.
[30]	IMAKITA K, KAMADA T, KAMATANI J I, et al.Room temperature direct imprinting of porous glassprepared from phase-separated glass [J]. Nanotechnology,2015, 26(25): 255304.
[37]	TSYGANOVA T A, ANTROPOVA T V, RAKHIMOVA O V, et al. Specific features of the formationof a porous structure in products of leaching of twophasesodium borosilicate glasses in acid-salt solutions[J]. Glass Physics and Chemistry, 2007, 33(2):122-129.
[31]	NOJI T, KAWAKAMI K, SHEN J R, et al. Oxygenevolvingporous glass plates containing the photosyntheticphotosystem II pigment-protein complex [J].Langmuir, 2016, 32(31): 7796-7805.
[38]	PORTER H H, EMERY N M. Method of treatingborosilicate glasses: US2215039 [P]. 1940-07-17[2018-05-12].
[32]	HWANG C, KIM J, RYU B K, et al. Preparationof porous glass films using phase separation phenomenonand growth behavior of phase-separatedstructure [J]. Journal of Materials Science, 2013,48(23): 8068-8076.
[39]	CHAPMAN I D, ELMER T H. Porous high silicaglass: US3485687 [P]. 1969-12-23 [2018-05-12].
[33]	BAL’ZHINIMAEV B S, SUKNEV A P, GULYAEVAY K, et al. Silicate fiberglass catalysts: From scienceto technology [J]. Catalysis in Industry, 2015, 7(4):267-274.
[34]	REINHARDT B, ENKE D, SYROWATKA F. Preparationof porous, hierarchically organized glass monolithsvia combination of sintering and phase separation[J]. Journal of the American Ceramic Society,2012, 95(2): 461-465.
[40]	EATON D L. Porous glass support material:US3904422 [P]. 1975-09-09 [2018-05-12].
[41]	CHE T M, CARNEY R V, DOTSON D L. Porousglass monoliths: US4810674 [P]. 1989-03-07 [2018-05-12].
[35]	POOLOGASUNDARAMPILLAI G, LEE P D, LAMC, et al. Compressive strength of bioactive sol-gelglass foam scaffolds [J]. International Journal of AppliedGlass Science, 2016, 7(2): 229-237.
[42]	ELMER T H, NORDBERG M E, CARRIER G B, etal. Phase separation in borosilicate glasses as seenby electron microscopy and scanning electron microscopy[J]. Journal of the American Ceramic Society,1970, 53(4): 171-175.
[36]	MARANGONIM, ARNOUT L, MACHIELS L, et al.Porous, sintered glass-ceramics from inorganic polymersbased on fayalite slag [J]. Journal of the AmericanCeramic Society, 2016, 99(6): 1985-1991.
[43]	YANG P D, DENG T, ZHAO D Y, et al. Hierarchicallyordered oxides [J]. Science, 1998, 282(5397):2244-2246.
[37]	TSYGANOVA T A, ANTROPOVA T V, RAKHIMOVA O V, et al. Specific features of the formationof a porous structure in products of leaching of twophasesodium borosilicate glasses in acid-salt solutions[J]. Glass Physics and Chemistry, 2007, 33(2):122-129.
[44]	YUN H S, KIM S E, HYEON Y T. Design andpreparation of bioactive glasses with hierarchical porenetworks [J]. Chemical Communications, 2007(21):2139-2141.
[45]	HALLER W. Rearrangement kinetics of the liquidliquidimmiscible microphases in alkali borosilicatemelts [J]. The Journal of Chemical Physics, 1965,42(2): 686-693.
[38]	PORTER H H, EMERY N M. Method of treatingborosilicate glasses: US2215039 [P]. 1940-07-17[2018-05-12].
[46]	CAHN JW. Phase separation by spinodal decompositionin isotropic systems [J]. The Journal of ChemicalPhysics, 1965, 42(1): 93-99.
[47]	CAHN JW, HILLIARD J E. Free energy of a nonuniformsystem. III. Nucleation in a two-componentincompressible fluid [J]. The Journal of ChemicalPhysics, 1959, 31(3): 688-699.
[39]	CHAPMAN I D, ELMER T H. Porous high silicaglass: US3485687 [P]. 1969-12-23 [2018-05-12].
[40]	EATON D L. Porous glass support material:US3904422 [P]. 1975-09-09 [2018-05-12].
[48]	YAZAWA T, KURAOKA K, DUW-F. Effect of coolingrate on pore distribution in quenched sodiumborosilicate glasses [J]. The Journal of PhysicalChemistry B, 1999, 103(45): 9841-9845.
[49]	KUKIZAKI M, NAKASHIMA T. Acid leachingprocess in the preparation of porous glass membranesfrom phase-separated glass in the Na2O-CaOMgO-Al2O3-B2O3-SiO2 system [J]. Membrane, 2004,29(5): 301-308.
[41]	CHE T M, CARNEY R V, DOTSON D L. Porousglass monoliths: US4810674 [P]. 1989-03-07 [2018-05-12].
[50]	PORTER H H, EMERY N M. Treated borosilicateglass: US2106744 [P]. 1938-02-01 [2018-05-12].
[42]	ELMER T H, NORDBERG M E, CARRIER G B, etal. Phase separation in borosilicate glasses as seenby electron microscopy and scanning electron microscopy[J]. Journal of the American Ceramic Society,1970, 53(4): 171-175.
[51]	IZUMI K, UTIYAMA M, MARUO Y Y. A porousglass-based ozone sensing chip impregnated withpotassium iodide and α-cyclodextrin [J]. Sensors andActuators B: Chemical, 2017, 241: 116-122.
[43]	YANG P D, DENG T, ZHAO D Y, et al. Hierarchicallyordered oxides [J]. Science, 1998, 282(5397):2244-2246.
[52]	SHEN C, WANG Y J, XU J H, et al. Synthesis of TS-1 on porous glass beads for catalytic oxidative desulfurization[J]. Chemical Engineering Journal, 2015,259: 552-561.
[44]	YUN H S, KIM S E, HYEON Y T. Design andpreparation of bioactive glasses with hierarchical porenetworks [J]. Chemical Communications, 2007(21):2139-2141.
[53]	SHEN C, WANG Y J, XU J H, et al. Oxidativedesulfurization of DBT with H2O2 catalyzed byTiO2/porous glass [J]. Green Chemistry, 2016, 18(3):771-781.
[45]	HALLER W. Rearrangement kinetics of the liquidliquidimmiscible microphases in alkali borosilicatemelts [J]. The Journal of Chemical Physics, 1965,42(2): 686-693.
[54]	JONES J R. New trends in bioactive scaffolds: Theimportance of nanostructure [J]. Journal of the EuropeanCeramic Society, 2009, 29(7): 1275-1281.
[46]	CAHN JW. Phase separation by spinodal decompositionin isotropic systems [J]. The Journal of ChemicalPhysics, 1965, 42(1): 93-99.
[55]	REICHELT E, HEDDRICH M P, JAHN M, et al.Fiber based structured materials for catalytic applications[J]. Applied Catalysis A: General, 2014, 476:78-90.
[47]	CAHN JW, HILLIARD J E. Free energy of a nonuniformsystem. III. Nucleation in a two-componentincompressible fluid [J]. The Journal of ChemicalPhysics, 1959, 31(3): 688-699.
[56]	SRIVASTAVA S K, GUIX M, SCHMIDT O G.Wastewater mediated activation of micromotors forefficient water cleaning [J]. Nano letters, 2016, 16(1):817-821.
[48]	YAZAWA T, KURAOKA K, DUW-F. Effect of coolingrate on pore distribution in quenched sodiumborosilicate glasses [J]. The Journal of PhysicalChemistry B, 1999, 103(45): 9841-9845.
[57]	SUN M H, HUANG S Z, CHEN L H, et al. Applicationsof hierarchically structured porous materialsfrom energy storage and conversion, catalysis,photocatalysis, adsorption, separation, and sensingto biomedicine [J]. Chemical Society Reviews, 2016,45(12): 3479-3563.
[49]	KUKIZAKI M, NAKASHIMA T. Acid leachingprocess in the preparation of porous glass membranesfrom phase-separated glass in the Na2O-CaOMgO-Al2O3-B2O3-SiO2 system [J]. Membrane, 2004,29(5): 301-308.
[58]	JACOB K, STOLLE A, ONDRUSCHKA B, et al.Cu on porous glass: An easily recyclable catalyst forthe microwave-assisted azide-alkyne cycloaddition inwater [J]. Applied Catalysis A: General, 2013, 451:94-100.
[50]	PORTER H H, EMERY N M. Treated borosilicateglass: US2106744 [P]. 1938-02-01 [2018-05-12].
[59]	LI J T, MAU A W H, STRAUSS C R. The use ofpalladium on porous glass for catalytic coupling reactions[J]. Chemical Communications, 1997 (14): 1275-1276.
[51]	IZUMI K, UTIYAMA M, MARUO Y Y. A porousglass-based ozone sensing chip impregnated withpotassium iodide and α-cyclodextrin [J]. Sensors andActuators B: Chemical, 2017, 241: 116-122.
[60]	SCHM¨OGER C, SZUPPA T, TIED A, et al. Pdon porous glass: A versatile and easily recyclablecatalyst for Suzuki and Heck reactions [J]. Chem-SusChem, 2008, 1(4): 339-347.
[52]	SHEN C, WANG Y J, XU J H, et al. Synthesis of TS-1 on porous glass beads for catalytic oxidative desulfurization[J]. Chemical Engineering Journal, 2015,259: 552-561.
[53]	SHEN C, WANG Y J, XU J H, et al. Oxidativedesulfurization of DBT with H2O2 catalyzed byTiO2/porous glass [J]. Green Chemistry, 2016, 18(3):771-781.
[61]	TAKAHASHI T, YAMASHITA K, KAI T, et al. Hydrogenationof benzene, mono-, di-, and trimethylbenzenesover nickel catalysts supported on porousglass [J]. The Canadian Journal of Chemical Engineering,1986, 64(6): 1008-1013.
[62]	YAMASHITA H, HONDA M, HARADA M, etal. Preparation of titanium oxide photocatalystsanchored on porous silica glass by a metal ionimplantationmethod and their photocatalytic reactivitiesfor the degradation of 2-propanol diluted inwater [J]. The Journal of Physical Chemistry B, 1998,102(52): 10707-10711.
[54]	JONES J R. New trends in bioactive scaffolds: Theimportance of nanostructure [J]. Journal of the EuropeanCeramic Society, 2009, 29(7): 1275-1281.
[63]	NAKAGAKI S, RAMOS A R, BENEDITO F L, et al.Immobilization of iron porphyrins into porous vycorglass: Characterization and study of catalytic activity[J]. Journal of Molecular Catalysis A: Chemical, 2002,185(1/2): 203-210.
[55]	REICHELT E, HEDDRICH M P, JAHN M, et al.Fiber based structured materials for catalytic applications[J]. Applied Catalysis A: General, 2014, 476:78-90.
[56]	SRIVASTAVA S K, GUIX M, SCHMIDT O G.Wastewater mediated activation of micromotors forefficient water cleaning [J]. Nano letters, 2016, 16(1):817-821.
[64]	SHEN C, WANG Y J, XU J H, et al. Size control andcatalytic activity of highly dispersed Pd nanoparticlessupported on porous glass beads [J]. Langmuir, 2012,28(19): 7519-7527.
[57]	SUN M H, HUANG S Z, CHEN L H, et al. Applicationsof hierarchically structured porous materialsfrom energy storage and conversion, catalysis,photocatalysis, adsorption, separation, and sensingto biomedicine [J]. Chemical Society Reviews, 2016,45(12): 3479-3563.
[65]	HAYASHIM, OCHIAI T, TAGO S, et al. Influence ofdissolved ions on the water purification performanceof TiO2-impregnated porous silica tubes [J]. Catalysts,2017, 7(5): 158.
[58]	JACOB K, STOLLE A, ONDRUSCHKA B, et al.Cu on porous glass: An easily recyclable catalyst forthe microwave-assisted azide-alkyne cycloaddition inwater [J]. Applied Catalysis A: General, 2013, 451:94-100.
[59]	LI J T, MAU A W H, STRAUSS C R. The use ofpalladium on porous glass for catalytic coupling reactions[J]. Chemical Communications, 1997 (14): 1275-1276.
[66]	OCHIAI T, TAGO S, HAYASHI M, et al. TiO2-Impregnated porous silica tube and its applicationfor compact air- and water-purification units [J]. Catalysts,2015, 5(3): 1498-1506.
[67]	PELTOLA S M, MELCHELS F P W, GRIJPMA DW, et al. A review of rapid prototyping techniques fortissue engineering purposes [J]. Annals of Medicine,2008, 40(4): 268-280.
[60]	SCHM¨OGER C, SZUPPA T, TIED A, et al. Pdon porous glass: A versatile and easily recyclablecatalyst for Suzuki and Heck reactions [J]. Chem-SusChem, 2008, 1(4): 339-347.
[68]	HUTMACHER D W. Scaffolds in tissue engineeringbone and cartilage [J]. Biomaterials, 2000, 21(24):2529-2543.
[61]	TAKAHASHI T, YAMASHITA K, KAI T, et al. Hydrogenationof benzene, mono-, di-, and trimethylbenzenesover nickel catalysts supported on porousglass [J]. The Canadian Journal of Chemical Engineering,1986, 64(6): 1008-1013.
[69]	BAINO F, FIORILLI S, VITALE-BROVARONEC. Bioactive glass-based materials with hierarchicalporosity for medical applications: Review of recentadvances [J]. Acta Biomaterialia, 2016, 42: 18-32.
[62]	YAMASHITA H, HONDA M, HARADA M, etal. Preparation of titanium oxide photocatalystsanchored on porous silica glass by a metal ionimplantationmethod and their photocatalytic reactivitiesfor the degradation of 2-propanol diluted inwater [J]. The Journal of Physical Chemistry B, 1998,102(52): 10707-10711.
[70]	ZHANG X D, ZENG D L, LI N, et al. Functionalizedmesoporous bioactive glass scaffolds for enhancedbone tissue regeneration [J]. Scientific Reports, 2016,6: 19361.
[63]	NAKAGAKI S, RAMOS A R, BENEDITO F L, et al.Immobilization of iron porphyrins into porous vycorglass: Characterization and study of catalytic activity[J]. Journal of Molecular Catalysis A: Chemical, 2002,185(1/2): 203-210.
[71]	ELSAYED H, ROMERO A R, FERRONI L, et al.Bioactive glass-ceramic scaffolds from novel ‘inorganicgel casting’ and sinter-crystallization [J]. Materials,2017, 10(2): 171.
[72]	JONES J R, EHRENFRIED L M, HENCH L L. Optimisingbioactive glass scaffolds for bone tissue engineering[J]. Biomaterials, 2006, 27(7): 964-973.
[64]	SHEN C, WANG Y J, XU J H, et al. Size control andcatalytic activity of highly dispersed Pd nanoparticlessupported on porous glass beads [J]. Langmuir, 2012,28(19): 7519-7527.
[73]	WU C T, XIA L G, HAN P P, et al. Europiumcontainingmesoporous bioactive glass scaffolds forstimulating in vitro and in vivo osteogenesis [J]. ACSApplied Materials & Interfaces, 2016, 8(18): 11342-11354.
[65]	HAYASHIM, OCHIAI T, TAGO S, et al. Influence ofdissolved ions on the water purification performanceof TiO2-impregnated porous silica tubes [J]. Catalysts,2017, 7(5): 158.
[74]	HENDRIKX S, KASCHOLKE C, FLATH T, et al.Indirect rapid prototyping of sol-gel hybrid glassscaffolds for bone regeneration: Effects of organiccrosslinker valence, content and molecular weight onmechanical properties [J]. Acta Biomaterialia, 2016,35: 318-329.
[66]	OCHIAI T, TAGO S, HAYASHI M, et al. TiO2-Impregnated porous silica tube and its applicationfor compact air- and water-purification units [J]. Catalysts,2015, 5(3): 1498-1506.
[67]	PELTOLA S M, MELCHELS F P W, GRIJPMA DW, et al. A review of rapid prototyping techniques fortissue engineering purposes [J]. Annals of Medicine,2008, 40(4): 268-280.
[75]	TSAI S W, CHANG Y H, YU J L, et al. Preparationof nanofibrous structure of mesoporous bioactive glassmicrobeads for biomedical applications [J]. Materials,2016, 9(6): 487.
[68]	HUTMACHER D W. Scaffolds in tissue engineeringbone and cartilage [J]. Biomaterials, 2000, 21(24):2529-2543.
[76]	WU C T, CHANG J. Multifunctional mesoporousbioactive glasses for effective delivery of therapeuticions and drug/growth factors [J]. Journal of ControlledRelease, 2014, 193: 282-295.
[69]	BAINO F, FIORILLI S, VITALE-BROVARONEC. Bioactive glass-based materials with hierarchicalporosity for medical applications: Review of recentadvances [J]. Acta Biomaterialia, 2016, 42: 18-32.
[77]	YANG S B, ZHAN L, XU X Y, et al. Graphenebasedporous silica sheets impregnated withpolyethyleneimine for superior CO2 capture [J].Advanced Materials, 2013, 25(15): 2130-2134.
[70]	ZHANG X D, ZENG D L, LI N, et al. Functionalizedmesoporous bioactive glass scaffolds for enhancedbone tissue regeneration [J]. Scientific Reports, 2016,6: 19361.
[78]	NUGENT P, BELMABKHOUT Y, BURD S D, et al.Porous materials with optimal adsorption thermodynamicsand kinetics for CO2 separation [J]. Nature,2013, 495(7439): 80-84.
[71]	ELSAYED H, ROMERO A R, FERRONI L, et al.Bioactive glass-ceramic scaffolds from novel ‘inorganicgel casting’ and sinter-crystallization [J]. Materials,2017, 10(2): 171.
[72]	JONES J R, EHRENFRIED L M, HENCH L L. Optimisingbioactive glass scaffolds for bone tissue engineering[J]. Biomaterials, 2006, 27(7): 964-973.
[79]	GAO X, ZOU X Q, MA H P, et al. Highly selectiveand permeable porous organic framework membranefor CO2 capture [J]. Advanced Materials, 2014,26(22): 3644-3648.
[80]	CHEN C, YANG S T, AHN W S, et al. Amineimpregnatedsilica monolith with a hierarchical porestructure: Enhancement of CO2 capture capacity [J].Chemical Communications, 2009(24): 3627-3629.
[73]	WU C T, XIA L G, HAN P P, et al. Europiumcontainingmesoporous bioactive glass scaffolds forstimulating in vitro and in vivo osteogenesis [J]. ACSApplied Materials & Interfaces, 2016, 8(18): 11342-11354.
[74]	HENDRIKX S, KASCHOLKE C, FLATH T, et al.Indirect rapid prototyping of sol-gel hybrid glassscaffolds for bone regeneration: Effects of organiccrosslinker valence, content and molecular weight onmechanical properties [J]. Acta Biomaterialia, 2016,35: 318-329.
[81]	ALKHABBAZMA, BOLLINI P, FOO G S, et al. Importantroles of enthalpic and entropic contributionsto CO2 capture from simulated flue gas and ambientair using mesoporous silica grafted amines [J]. Journalof the American Chemical Society, 2014, 136(38):13170-13173.
[82]	SPENIK J L, SHADLE L J, BREAULT R W, et al.Cyclic tests in batch mode of CO2 adsorption andregeneration with sorbent consisting of immobilizedamine on a mesoporous silica [J]. Industrial & EngineeringChemistry Research, 2015, 54(20): 5388-5397.
[75]	TSAI S W, CHANG Y H, YU J L, et al. Preparationof nanofibrous structure of mesoporous bioactive glassmicrobeads for biomedical applications [J]. Materials,2016, 9(6): 487.
[83]	ZELEˇN ′AK V, BADANIˇCOV′A M, HALAMOV′A D,et al. Amine-modified ordered mesoporous silica: Effectof pore size on carbon dioxide capture [J]. ChemicalEngineering Journal, 2008, 144(2): 336-342.
[76]	WU C T, CHANG J. Multifunctional mesoporousbioactive glasses for effective delivery of therapeuticions and drug/growth factors [J]. Journal of ControlledRelease, 2014, 193: 282-295.
[77]	YANG S B, ZHAN L, XU X Y, et al. Graphenebasedporous silica sheets impregnated withpolyethyleneimine for superior CO2 capture [J].Advanced Materials, 2013, 25(15): 2130-2134.
[84]	MINJU N, ABHILASH P, NAIR B N, et al. Amine impregnated porous silica gel sorbents synthesizedfrom water-glass precursors for CO2 capturing [J].Chemical Engineering Journal, 2015, 269: 335-342.
[78]	NUGENT P, BELMABKHOUT Y, BURD S D, et al.Porous materials with optimal adsorption thermodynamicsand kinetics for CO2 separation [J]. Nature,2013, 495(7439): 80-84.
[85]	ZELENAK V, HALAMOVA D, GABEROVA L, et al.Amine-modified SBA-12 mesoporous silica for carbondioxide capture: Effect of amine basicity on sorptionproperties [J]. Microporous and Mesoporous Materials,2008, 116(1/2/3): 358-364.
[79]	GAO X, ZOU X Q, MA H P, et al. Highly selectiveand permeable porous organic framework membranefor CO2 capture [J]. Advanced Materials, 2014,26(22): 3644-3648.
[86]	CHANG F Y, CHAO K J, CHENG H H, et al. Adsorptionof CO2 onto amine-grafted mesoporous silicas[J]. Separation and Purification Technology, 2009,70(1): 87-95.
[80]	CHEN C, YANG S T, AHN W S, et al. Amineimpregnatedsilica monolith with a hierarchical porestructure: Enhancement of CO2 capture capacity [J].Chemical Communications, 2009(24): 3627-3629.
[87]	MELLO M R, PHANON D, SILVEIRA G Q, et al.Amine-modified MCM-41 mesoporous silica for carbondioxide capture [J]. Microporous and MesoporousMaterials, 2011, 143(1): 174-179.
[81]	ALKHABBAZMA, BOLLINI P, FOO G S, et al. Importantroles of enthalpic and entropic contributionsto CO2 capture from simulated flue gas and ambientair using mesoporous silica grafted amines [J]. Journalof the American Chemical Society, 2014, 136(38):13170-13173.
[88]	CHAIKITTISILP W, KHUNSUPAT R, CHEN T T,et al. Poly(allylamine)-mesoporous silica compositematerials for CO2 capture from simulated flue gas orambient air [J]. Industrial & Engineering ChemistryResearch, 2011, 50(24): 14203-14210.
[89]	BRUNELLI N A, DIDAS S A, VENKATASUBBAIAHK, et al. Tuning cooperativity by controlling thelinker length of silica-supported amines in catalysisand CO2 capture [J]. Journal of the American ChemicalSociety, 2012, 134(34): 13950-13953.
[82]	SPENIK J L, SHADLE L J, BREAULT R W, et al.Cyclic tests in batch mode of CO2 adsorption andregeneration with sorbent consisting of immobilizedamine on a mesoporous silica [J]. Industrial & EngineeringChemistry Research, 2015, 54(20): 5388-5397.
[83]	ZELEˇN ′AK V, BADANIˇCOV′A M, HALAMOV′A D,et al. Amine-modified ordered mesoporous silica: Effectof pore size on carbon dioxide capture [J]. ChemicalEngineering Journal, 2008, 144(2): 336-342.
[90]	FAUTH D J, GRAY M L, PENNLINE H W, et al.Investigation of porous silica supported mixed-aminesorbents for post-combustion CO2 capture [J]. Energy& Fuels, 2012, 26(4): 2483-2496.
[91]	JI C C, HUANG X, LI L, et al.Pentaethylenehexamine-loaded hierarchically poroussilica for CO2 adsorption [J]. Materials, 2016, 9(10):835.
[84]	MINJU N, ABHILASH P, NAIR B N, et al. Amine impregnated porous silica gel sorbents synthesizedfrom water-glass precursors for CO2 capturing [J].Chemical Engineering Journal, 2015, 269: 335-342.
[92]	SHEN C, WANG Y J, XU J H, et al. Porous glassbeads as a new adsorbent to remove sulfur-containingcompounds [J]. Green Chemistry, 2012, 14(4): 1009-1015.
[85]	ZELENAK V, HALAMOVA D, GABEROVA L, et al.Amine-modified SBA-12 mesoporous silica for carbondioxide capture: Effect of amine basicity on sorptionproperties [J]. Microporous and Mesoporous Materials,2008, 116(1/2/3): 358-364.
[86]	CHANG F Y, CHAO K J, CHENG H H, et al. Adsorptionof CO2 onto amine-grafted mesoporous silicas[J]. Separation and Purification Technology, 2009,70(1): 87-95.
[93]	SHEN C, WANG Y J, XU J H, et al. Chitosan supportedon porous glass beads as a new green adsorbentfor heavy metal recovery [J]. Chemical EngineeringJournal, 2013, 229: 217-224.
[94]	LI L Y, CHEN L, SHI H R, et al. Evaluation of mesoporousbioactive glass (MBG) as adsorbent for removalof methylene blue (MB) from aqueous solution[J]. Journal of Environmental Chemical Engineering,2016, 4(2): 1451-1459.
[87]	MELLO M R, PHANON D, SILVEIRA G Q, et al.Amine-modified MCM-41 mesoporous silica for carbondioxide capture [J]. Microporous and MesoporousMaterials, 2011, 143(1): 174-179.
[95]	ZADAKA D, MISHAEL Y G, POLUBESOVA T, etal. Modified silicates and porous glass as adsorbentsfor removal of organic pollutants from water and comparisonwith activated carbons [J]. Applied Clay Science,2007, 36(1): 174-181.
[88]	CHAIKITTISILP W, KHUNSUPAT R, CHEN T T,et al. Poly(allylamine)-mesoporous silica compositematerials for CO2 capture from simulated flue gas orambient air [J]. Industrial & Engineering ChemistryResearch, 2011, 50(24): 14203-14210.
[96]	PASETA L, SIM′ON-GAUD′O E, GRACIA-GORR′IAF, et al. Encapsulation of essential oils in porous silicaand MOFs for trichloroisocyanuric acid tablets usedfor water treatment in swimming pools [J]. ChemicalEngineering Journal, 2016, 292: 28-34.
[89]	BRUNELLI N A, DIDAS S A, VENKATASUBBAIAHK, et al. Tuning cooperativity by controlling thelinker length of silica-supported amines in catalysisand CO2 capture [J]. Journal of the American ChemicalSociety, 2012, 134(34): 13950-13953.
[97]	DOU J, ZENG H C. Integrated networks ofmesoporous silica nanowires and their bifunctionalcatalysis-sorption application for oxidative desulfurization[J]. ACS Catalysis, 2014, 4(2): 566-576.
[90]	FAUTH D J, GRAY M L, PENNLINE H W, et al.Investigation of porous silica supported mixed-aminesorbents for post-combustion CO2 capture [J]. Energy& Fuels, 2012, 26(4): 2483-2496.
[98]	ZHANG F, SONG J, CHEN M, et al. Enhanced perovskitemorphology and crystallinity for high performanceperovskite solar cells using a porous hole transportlayer from polystyrene nanospheres [J]. PhysicalChemistry Chemical Physics, 2016, 18(48): 32903-32909.
[91]	JI C C, HUANG X, LI L, et al.Pentaethylenehexamine-loaded hierarchically poroussilica for CO2 adsorption [J]. Materials, 2016, 9(10):835.
[99]	REUILLARD B, LY K H, HILDEBRANDT P, et al.High performance reduction of H2O2 with an electrontransport decaheme cytochrome on a porousITO electrode [J]. Journal of the American ChemicalSociety, 2017, 139(9): 3324-3327.
[92]	SHEN C, WANG Y J, XU J H, et al. Porous glassbeads as a new adsorbent to remove sulfur-containingcompounds [J]. Green Chemistry, 2012, 14(4): 1009-1015.
[100]	M¨ULLER R, ANDERS N, TITUS J, et al. Ultrathinporous glass membranes: An innovative materialfor the immobilization of active species for opticalchemosensors [J]. Talanta, 2013, 107: 255-262.
[101]	DE EULATE E A, STRUTWOLF J, LIU Y, etal. An electrochemical sensing platform based onliquid-liquid microinterface arrays formed in laserablatedglass membranes [J]. Analytical Chemistry,2016, 88(5): 2596-2604.
[93]	SHEN C, WANG Y J, XU J H, et al. Chitosan supportedon porous glass beads as a new green adsorbentfor heavy metal recovery [J]. Chemical EngineeringJournal, 2013, 229: 217-224.
[102]	ZHANG X D, XU X L, HE W, et al.LiFePO4/NaFe3V9O19/porous glass nanocompositecathodes for Li+/Na+ mixed-ion batteries[J]. Journal of Materials Chemistry A, 2015, 3:22247-22257.
[94]	LI L Y, CHEN L, SHI H R, et al. Evaluation of mesoporousbioactive glass (MBG) as adsorbent for removalof methylene blue (MB) from aqueous solution[J]. Journal of Environmental Chemical Engineering,2016, 4(2): 1451-1459.
[103]	GASPERA E D, BUSO D, GUGLIELMI M, et al.Comparison study of conductometric, optical andSAW gas sensors based on porous sol-gel silica filmsdoped with NiO and Au nanocrystals [J]. Sensors andActuators B: Chemical, 2010, 143(2): 567-573.
[95]	ZADAKA D, MISHAEL Y G, POLUBESOVA T, etal. Modified silicates and porous glass as adsorbentsfor removal of organic pollutants from water and comparisonwith activated carbons [J]. Applied Clay Science,2007, 36(1): 174-181.
[104]	DE STEFANO L, MALECKI K, DELLA CORTE FG, et al. A microsystem based on porous silicon-glassanodic bonding for gas and liquid optical sensing [J].Sensors, 2006, 6(6): 680-687.
[96]	PASETA L, SIM′ON-GAUD′O E, GRACIA-GORR′IAF, et al. Encapsulation of essential oils in porous silicaand MOFs for trichloroisocyanuric acid tablets usedfor water treatment in swimming pools [J]. ChemicalEngineering Journal, 2016, 292: 28-34.
[105]	ABDELGHANI A, CHOVELON J M, JAFFREZICRENAULT N, et al. Optical fibre sensor coated withporous silica layers for gas and chemical vapour detection[J]. Sensors and Actuators B: Chemical, 1997,44(1/2/3): 495-498.
[97]	DOU J, ZENG H C. Integrated networks ofmesoporous silica nanowires and their bifunctionalcatalysis-sorption application for oxidative desulfurization[J]. ACS Catalysis, 2014, 4(2): 566-576.
[106]	RAYSS J, SUDOLSKI G. Ion adsorption in theporous sol-gel silica layer in the fibre optic pH sensor[J]. Sensors and Actuators B: Chemical, 2002, 87(3):397-405.
[98]	ZHANG F, SONG J, CHEN M, et al. Enhanced perovskitemorphology and crystallinity for high performanceperovskite solar cells using a porous hole transportlayer from polystyrene nanospheres [J]. PhysicalChemistry Chemical Physics, 2016, 18(48): 32903-32909.
[107]	SARMA T V S, TAO S Q. An active core fiber opticsensor for detecting trace H2S at high temperatureusing a cadmium oxide doped porous silica opticalfiber as a transducer [J]. Sensors and Actuators B:Chemical, 2007, 127(2): 471-479.
[108]	ESTELLA J, DE VICENTE P, ECHEVERR′IA J C,et al. A fibre-optic humidity sensor based on a poroussilica xerogel film as the sensing element [J]. Sensorsand Actuators B: Chemical, 2010, 149(1): 122-128.
[99]	REUILLARD B, LY K H, HILDEBRANDT P, et al.High performance reduction of H2O2 with an electrontransport decaheme cytochrome on a porousITO electrode [J]. Journal of the American ChemicalSociety, 2017, 139(9): 3324-3327.
[109]	CHEN Y Z, LI X J, ZHOU H S, et al. Refractive index detection range adjustable liquid-core fiber optic sensor based on surface plasmon resonance and a nano-porous silica coating [J]. Journal of Physics D:Applied Physics, 2016, 49(35): 355102.
[100]	M¨ULLER R, ANDERS N, TITUS J, et al. Ultrathinporous glass membranes: An innovative materialfor the immobilization of active species for opticalchemosensors [J]. Talanta, 2013, 107: 255-262.
[101]	DE EULATE E A, STRUTWOLF J, LIU Y, etal. An electrochemical sensing platform based onliquid-liquid microinterface arrays formed in laserablatedglass membranes [J]. Analytical Chemistry,2016, 88(5): 2596-2604.
[110]	ECHEVERR′IA J C, FAUSTINI M, GARRIDO J J.Effects of the porous texture and surface chemistry ofsilica xerogels on the sensitivity of fiber-optic sensorstoward VOCs [J]. Sensors and Actuators B: Chemical,2016, 222: 1166-1174.
[102]	ZHANG X D, XU X L, HE W, et al.LiFePO4/NaFe3V9O19/porous glass nanocompositecathodes for Li+/Na+ mixed-ion batteries[J]. Journal of Materials Chemistry A, 2015, 3:22247-22257.
[111]	CRAMP J H W, MURRAY R T, REID R F, et al.Fibre optic sensor with bonded dye: US4560248 [P].1985-12-24 [2018-05-12].
[112]	SIGEL JR G, SHAHRIARIM, ZHOU Q. Method formaking porous glass optical fiber sensor: US5250095[P]. 1993-10-05 [2018-05-12].
[103]	GASPERA E D, BUSO D, GUGLIELMI M, et al.Comparison study of conductometric, optical andSAW gas sensors based on porous sol-gel silica filmsdoped with NiO and Au nanocrystals [J]. Sensors andActuators B: Chemical, 2010, 143(2): 567-573.
[113]	BURNS A A, HERZ E, ZEDAYKO T C, et al. Photoluminescentsilica-based sensors and methods of use:US8084001 [P]. 2011-12-27 [2018-05-12].
[104]	DE STEFANO L, MALECKI K, DELLA CORTE FG, et al. A microsystem based on porous silicon-glassanodic bonding for gas and liquid optical sensing [J].Sensors, 2006, 6(6): 680-687.
[114]	XU P C, LI X X, YU H T, et al. Advancednanoporous materials for micro-gravimetric sensingto trace-level bio/chemical molecules [J]. Sensors,2014, 14(10): 19023-19056.
[105]	ABDELGHANI A, CHOVELON J M, JAFFREZICRENAULT N, et al. Optical fibre sensor coated withporous silica layers for gas and chemical vapour detection[J]. Sensors and Actuators B: Chemical, 1997,44(1/2/3): 495-498.
[115]	WAGNER T, KROTZKY S, WEI S S A, et al. A high temperature capacitive humidity sensor basedon mesoporous silica [J]. Sensors, 2011, 11(3): 3135-3144.
[106]	RAYSS J, SUDOLSKI G. Ion adsorption in theporous sol-gel silica layer in the fibre optic pH sensor[J]. Sensors and Actuators B: Chemical, 2002, 87(3):397-405.
[116]	ADDANKI S, NEDUMARAN D. Fabrication ofozone sensors on porous glass substrates using goldand silver thin films nanoislands [J]. Optik, 2017, 150:11-21.
[107]	SARMA T V S, TAO S Q. An active core fiber opticsensor for detecting trace H2S at high temperatureusing a cadmium oxide doped porous silica opticalfiber as a transducer [J]. Sensors and Actuators B:Chemical, 2007, 127(2): 471-479.
[117]	IZUMI K, UTIYAMA M, MARUO Y Y. A porousglass-based KI/α-CD chip for ozone sensing: Improvementin the humidity response of the chipthrough optimizing reagent concentrations in the impregnationprocess [J]. Sensors and Actuators B:Chemical, 2018, 268: 1-6.
[108]	ESTELLA J, DE VICENTE P, ECHEVERR′IA J C,et al. A fibre-optic humidity sensor based on a poroussilica xerogel film as the sensing element [J]. Sensorsand Actuators B: Chemical, 2010, 149(1): 122-128.
[118]	ZHU X B, ZHAO T S, WEI Z H, et al. A novel solidstateLi-O2 battery with an integrated electrolyte andcathode structure [J]. Energy & Environmental Science,2015, 8(9): 2782-2790.
[109]	CHEN Y Z, LI X J, ZHOU H S, et al. Refractive index detection range adjustable liquid-core fiber optic sensor based on surface plasmon resonance and a nano-porous silica coating [J]. Journal of Physics D:Applied Physics, 2016, 49(35): 355102.
[119]	LI G X, SUN J H, HOUWP, et al. Three-dimensionalporous carbon composites containing high sulfurnanoparticle content for high-performance lithiumsulfurbatteries [J]. Nature Communications, 2016, 7:10601.
[110]	ECHEVERR′IA J C, FAUSTINI M, GARRIDO J J.Effects of the porous texture and surface chemistry ofsilica xerogels on the sensitivity of fiber-optic sensorstoward VOCs [J]. Sensors and Actuators B: Chemical,2016, 222: 1166-1174.
[120]	YUAN Z Z, DUAN Y Q, ZHANG H Z, et al. Advancedporous membranes with ultra-high selectivityand stability for vanadium flow batteries [J]. Energy& Environmental Science, 2016, 9(2): 441-447.
[111]	CRAMP J H W, MURRAY R T, REID R F, et al.Fibre optic sensor with bonded dye: US4560248 [P].1985-12-24 [2018-05-12].
[121]	WANG G L, BOHATY A K, ZHAROV I, et al. Photongated transport at the glass nanopore electrode[J]. Journal of the American Chemical Society, 2006,128(41): 13553-13558.
[112]	SIGEL JR G, SHAHRIARIM, ZHOU Q. Method formaking porous glass optical fiber sensor: US5250095[P]. 1993-10-05 [2018-05-12].
[113]	BURNS A A, HERZ E, ZEDAYKO T C, et al. Photoluminescentsilica-based sensors and methods of use:US8084001 [P]. 2011-12-27 [2018-05-12].
[122]	SORGE M, BEAN T, WOODLAND T, et al. Investigatingthe use of porous, hollow glass microspheres inpositive lead acid battery plates [J]. Journal of PowerSources, 2014, 266: 496-511.
[123]	LU J, FAN Y S, HOWARD M D, et al. Singlemoleculeelectrochemistry on a porous silica-coatedelectrode [J]. Journal of the American Chemical Society,2017, 139(8): 2964-2971.
[114]	XU P C, LI X X, YU H T, et al. Advancednanoporous materials for micro-gravimetric sensingto trace-level bio/chemical molecules [J]. Sensors,2014, 14(10): 19023-19056.
[124]	SCHADECK U, KYRGYZBAEV K, GERDES T,et al. Porous and non-porous micrometer-sized glassplatelets as separators for lithium-ion batteries [J].Journal of Membrane Science, 2018, 550: 518-525.
[115]	WAGNER T, KROTZKY S, WEI S S A, et al. A high temperature capacitive humidity sensor basedon mesoporous silica [J]. Sensors, 2011, 11(3): 3135-3144.
[116]	ADDANKI S, NEDUMARAN D. Fabrication ofozone sensors on porous glass substrates using goldand silver thin films nanoislands [J]. Optik, 2017, 150:11-21.
[125]	KIM J, LEE S, SHIN D. Preparation of a hybrid solidglass electrolyte using a nano-porous sodium borosilicateglass membrane for lithium batteries [J]. Journalof Ceramic Processing Research, 2007, 8(3): 208-212.
[117]	IZUMI K, UTIYAMA M, MARUO Y Y. A porousglass-based KI/α-CD chip for ozone sensing: Improvementin the humidity response of the chipthrough optimizing reagent concentrations in the impregnationprocess [J]. Sensors and Actuators B:Chemical, 2018, 268: 1-6.
[126]	WU L P, ZHANGW, ZHANG D. Engineering gyroidstructuredfunctional materials via templates discoveredin nature and in the lab [J]. Small, 2015, 11(38):5004-5022.
[118]	ZHU X B, ZHAO T S, WEI Z H, et al. A novel solidstateLi-O2 battery with an integrated electrolyte andcathode structure [J]. Energy & Environmental Science,2015, 8(9): 2782-2790.
[119]	LI G X, SUN J H, HOUWP, et al. Three-dimensionalporous carbon composites containing high sulfurnanoparticle content for high-performance lithiumsulfurbatteries [J]. Nature Communications, 2016, 7:10601.
[120]	YUAN Z Z, DUAN Y Q, ZHANG H Z, et al. Advancedporous membranes with ultra-high selectivityand stability for vanadium flow batteries [J]. Energy& Environmental Science, 2016, 9(2): 441-447.
[121]	WANG G L, BOHATY A K, ZHAROV I, et al. Photongated transport at the glass nanopore electrode[J]. Journal of the American Chemical Society, 2006,128(41): 13553-13558.
[122]	SORGE M, BEAN T, WOODLAND T, et al. Investigatingthe use of porous, hollow glass microspheres inpositive lead acid battery plates [J]. Journal of PowerSources, 2014, 266: 496-511.
[123]	LU J, FAN Y S, HOWARD M D, et al. Singlemoleculeelectrochemistry on a porous silica-coatedelectrode [J]. Journal of the American Chemical Society,2017, 139(8): 2964-2971.
[124]	SCHADECK U, KYRGYZBAEV K, GERDES T,et al. Porous and non-porous micrometer-sized glassplatelets as separators for lithium-ion batteries [J].Journal of Membrane Science, 2018, 550: 518-525.
[125]	KIM J, LEE S, SHIN D. Preparation of a hybrid solidglass electrolyte using a nano-porous sodium borosilicateglass membrane for lithium batteries [J]. Journalof Ceramic Processing Research, 2007, 8(3): 208-212.
[126]	WU L P, ZHANGW, ZHANG D. Engineering gyroidstructuredfunctional materials via templates discoveredin nature and in the lab [J]. Small, 2015, 11(38):5004-5022.