Abstract: In this study, the temperature and gas velocity distributions in hot filament chemical vapor deposition (HFCVD) diamond film growth on the end surfaces of seals are simulated by the finite volume method. The influence of filament diameter, filament separation and rotational speed of the substrates is considered. Firstly, the simulation model is established by simplifying operating conditions to simulate the temperature and gas velocity distributions. Thereafter, the deposition parameters are optimized as 0.6mm filament diameter, 18mm filament separation and 5 r/min rotational speed to get the uniform temperature distribution. Under the influence of the rotational speed, the difference between temperature gradients along the directions perpendicular to the filament and parallel to the filament becomes narrow, it is consistent with the actual condition, and the maximum temperature difference on the substrates decreases to 7.4 ◦C. Furthermore, the effect of the rotational speed on the gas velocity distribution is studied. Finally, diamond films are deposited on the end surfaces of SiC seals with the optimized deposition parameters. The characterizations by scanning electron microscopy (SEM) and Raman spectroscopy exhibit a layer of homogeneous diamond films with fine-faceted crystals and uniform thickness. The results validate the simulation model. © 2016, Shanghai Jiaotong University and Springer-Verlag Berlin Heidelberg.

Key words: finite volume method; hot filament chemical vapor deposition (HFCVD); rotational speed; substrate temperature; velocity field distribution