上海交通大学学报

上海交通大学学报（自然版）

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La2Cu1-xLixO4+δ体系低频内耗研究

陈志军1,2，杨春利1，吴修胜1，刘卫1   

  1. （1.中国科学技术大学 中国科学院能源转换材料重点实验室，合肥 230026；2.安徽省绩溪中学，安徽 宣城 245300）
  • 收稿日期:2009-05-10 修回日期:1900-01-01 出版日期:2010-05-31 发布日期:2010-05-31

CHEN Zhijun1,2，YANG Chunli1，WU Xiusheng1，LIU Wei1   

  1. (1. Key Lab of Energy Conversion Materials, Chinese Academy of Sciences, University of Science and Technology of China, Hefei 230026, China; 2. Anhui Jixi High School, Xuancheng 245300, Anhui, China)
  • Received:2009-05-10 Revised:1900-01-01 Online:2010-05-31 Published:2010-05-31

摘要： 采用强迫振动方法对La2Cu1-xLixO4+δ(0.02≤x≤0.15)系列氧化物超导体的母体化合物的低频内耗和模量进行了研究.结果表明，当x=0.02,0.05时，La2Cu1-xLixO4+δ在250 K附近存在一个弛豫型内耗峰P1，为共价氧对形式的额外氧跳跃弛豫运动的结果；当x=0.10,0.15时，La2Cu1-xLixO4+δ除了存在内耗峰P1外，在200 K附近还出现了内耗峰P2；La2Cu1-xLixO4+δ在高温区域的模量反常现象反映了体系的正交与四方结构转变，其相变温度随Li的掺杂量的增加而向低温区域移动.

关键词: 氧化物超导体, 无损检测, 额外氧, 内耗, 相变

Abstract: The lowfrequency internal friction Q-1 and relative shear modulus E of La2Cu1-xLixO4+δ (0.02≤x≤0.15) compounds were studied by means of force fibration. For x=0.02 and 0.05, only one relaxation peak exists around 250 K and this peak is due to the hopping of O pairs. For x=0.1 and 0.15, apart from the peak P1, another peak P2 is observed at 200 K. In addition, the position of the structure phase transition revealed by shear modulus moves to lower temperature side with the Li content increasing.

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