This paper presents quantitatively the results of an experimental investigation on influence of mineral
admixtures and superplasticizers on Vickers micro hardness (HV) of aggregate-paste interface in cement concrete.
The HV was measured by Vickers hardness testing equipment. The results indicate that addition of fly ash
decreases HV of the concrete. Although it decreases with the increase of ground granulated blast furnace slag
(GGBS) replacement, the HV is higher than that of concrete containing fly ash at all replacements. The flying ash
and GGBS composition increases HV in later curing ages, but does not improve it in early curing ages. Aminosulfonic
acid based superplasticizer and aliphatic hydroxy sulphonate condensate superplasticizer can enhance HV
in early curing ages. The HV of concrete with polycarboxylic acid superplasticizer is higher in later curing ages.
WANG Zhen-jun* (王振军), WANG Qiong (王琼), WEI Yong-feng (魏永锋)
. Effects of Mineral Admixtures and Superplasticizers on
Micro Hardness of Aggregate-Paste Interface in Cement Concrete[J]. Journal of Shanghai Jiaotong University(Science), 2012
, 17(5)
: 629
-634
.
DOI: 10.1007/s12204-012-1335-4
[1] Wong Y L, Lam L, Poon C S, et al. Properties of fly ash-modified cement mortar-aggregate interfaces [J].Cement and Concrete Research, 1999, 29(12): 1905-1913.
[2] Stevula L, Madej J, Kozankova J, et al. Hydration products at the blast furnace slag aggregate-cement paste interface [J]. Cement and Concrete Research,1994, 24(3): 413-423.
[3] Qian Chun-xiang, Huang Bei, Dong Hua. Influence of size and shape of aggregate and mineral admixture on interface of concrete [J]. Journal of Southeast University:Natural Science Edition, 2009, 39(4): 840-843(in Chinese).
[4] Zheng Ke-ren, Sun Wei, Lin Wei, et al. Effects of blast furnace slag on micro-mechanical properties of interface transition zone [J]. Journal of Nanjing University of Aeronautics and Astronautics, 2008, 40(3):407-411 (in Chinese).
[5] Kilinc?ale F M, Dogan G G. Performance of concretes produced with superplasticizer [J]. Journal of Applied Polymer Science, 2007, 103(5): 3214-3219.
[6] Prokopski G, Halbiniak J. Interfacial transition zone in cementitious materials [J]. Cement and Concrete Research, 2000, 30(4): 579-583.
[7] Shah S P, Li Z, Lange D A. Properties of aggregatecement interface for high performance concrete [C]//Proceedings of the 9th Conference on Engineering Mechanics.Texas, USA: ASCE, 1992: 852-855.
[8] Larbi J A, Bijen J M. Orientation of calcium hydroxide at the Portland cement paste-aggregate interface in mortars in the presence of silica fume [J].Cement and Concrete Research, 1990, 20(3): 461-470.
[9] Aligizaki K K, De R M R, Macdonald D D. Analysis of iron oxides accumulating at the interface between aggregates and cement paste [J]. Cement and Concrete Research, 2000, 30(12): 1941-1945.
[10] Diamond S. Considerations in image analysis as applied to investigations of the ITZ in concrete [J].Cement and Concrete Composites, 2001, 23(2-3): 171-178.
[11] Scrivener K L. Backscattered electron imaging of cementitious microstructures: Understanding and quantification [J]. Cement and Concrete Composites, 2004,26(8): 935-945.
[12] Xing F, Quo X Y, Leng F G, et al. Study on distribution feature of fracture toughness of interface between coarse aggregate and hardened cement mortar in concrete[J]. Key Engineering Materials, 2006: 302-303,514-520.
[13] Chen Hui-su, Sun Wei, Zhao Qing-xin. Analytical solution on the overestimation of thickness of interfacial transition zone around grain with arbitrary convex shape by the section analysis method [J]. Acta Materiae Compositae Sinica, 2006, 23(4): 155-163 (in Chinese).
[14] Chen Wei, Tian Ya-po, Zhou Zi-chen. Carbonation of fly ash concrete and micro hardness analysis [J]. Journal of Wuhan University of Technology, 2009, 31(11):48-51 (in Chinese).
[15] Igarashi S, Bentur A, Mindess S. Microhardness testing of cementitious materials [J]. Advanced Cement Based Materials, 1996, 4(2): 48-57.
[16] Igarashi S, Bentur A, Mindess S. Characterization of the microstructure and strength of cement paste by micro hardness testing [J]. Advances in Cement Research,1996, 30(8): 87-92.
[17] Glinicki M A, Zielinski M. Depth-sensing indentation method for evaluation of efficiency of secondary cementitious materials [J]. Cement and Concrete Research,2004, 34(4): 721-724.
[18] Lian Li, Yin Hai-chun, Liao Wei-dong. Study on micro hardness of interface zone in cement concrete [J].Science and Technology of Overseas Building Materials,2005, 26(2): 8-11 (in Chinese).
[19] Velez K, Maximilien S, Damidot D, et al. Determination by nano indentation of elastic modulus and hardness of pure constituents of Portland cement clinker [J]. Cement and Concrete Research, 2001,31(4): 555-561.
[20] Yuan Run-zhang. Binding materials [M]. Wuhan:Press of Wuhan University of Technology, 1996 (in Chinese).