Study on Oxidation Activity of CuCeZrOx Doped with K for Diesel Engine Particles in NO/O2

doi:10.1007/s12204-018-2018-6

摘要/Abstract

摘要： CuCeZrOx and KCuCeZrOx catalysts were synthesized and coated on the blank diesel particulate filter (DPF) substrate and a particulate matter (PM) loading apparatus was used for soot loading. The catalytic performances of soot oxidation were evaluated by temperature programmed combustion (TPC) test and characterization tests were conducted to investigate the physicochemical properties of the catalysts. The reaction mechanism in the oxidation process was analyzed with diffuse reflectance infrared Fourier transform spectroscopy. The results demonstrated that CuCeZrOx catalyst exhibited high activities of soot oxidation at low temperature and the best results have been attained with Cu0.9Ce0.05Zr0.05Ox over which the maximum soot oxidation rate decreased to 410°C. Characterization tests have shown that catalysts containing 90% Cu have uniformly distributed grains and small particle sizes, which provide excellent oxidation activity by providing more active sites and forming a good bond between the catalyst and the soot. The low-temperature oxidation activity of soot could be further optimized due to the excellent elevated NO’s conversion rate by partially substituting Cu with K. The maximum particle oxidation rate can be easily realized at such a low temperature as 347°C.

关键词: self-propagating high-temperature synthesis (SHS) , Mn and Ce substitution , low temperature activity , N2 selectivity , H2O and SO2 poisoning , in situ diffused reflectance infrared Fourier transform spectroscopy (DRIFTS)

Abstract: CuCeZrOx and KCuCeZrOx catalysts were synthesized and coated on the blank diesel particulate filter (DPF) substrate and a particulate matter (PM) loading apparatus was used for soot loading. The catalytic performances of soot oxidation were evaluated by temperature programmed combustion (TPC) test and characterization tests were conducted to investigate the physicochemical properties of the catalysts. The reaction mechanism in the oxidation process was analyzed with diffuse reflectance infrared Fourier transform spectroscopy. The results demonstrated that CuCeZrOx catalyst exhibited high activities of soot oxidation at low temperature and the best results have been attained with Cu0.9Ce0.05Zr0.05Ox over which the maximum soot oxidation rate decreased to 410°C. Characterization tests have shown that catalysts containing 90% Cu have uniformly distributed grains and small particle sizes, which provide excellent oxidation activity by providing more active sites and forming a good bond between the catalyst and the soot. The low-temperature oxidation activity of soot could be further optimized due to the excellent elevated NO’s conversion rate by partially substituting Cu with K. The maximum particle oxidation rate can be easily realized at such a low temperature as 347°C.

Key words: self-propagating high-temperature synthesis (SHS) , Mn and Ce substitution , low temperature activity , N2 selectivity , H2O and SO2 poisoning , in situ diffused reflectance infrared Fourier transform spectroscopy (DRIFTS)

中图分类号:

TK 421.5

WANG Kexin (王可欣), GUAN Bin (管斌), LI Ke (李珂), ZHAN Rijing (湛日景), LIN He (林赫), HUA. Study on Oxidation Activity of CuCeZrOx Doped with K for Diesel Engine Particles in NO/O2[J]. Journal of Shanghai Jiao Tong University (Science), 2018, 23(Sup. 1): 18-27.

WANG Kexin (王可欣), GUAN Bin (管斌), LI Ke (李珂), ZHAN Rijing (湛日景), LIN He (林赫), HUANG Zhen (黄震). Study on Oxidation Activity of CuCeZrOx Doped with K for Diesel Engine Particles in NO/O2[J]. Journal of Shanghai Jiao Tong University (Science), 2018, 23(Sup. 1): 18-27.

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