上海交通大学学报(英文版) ›› 2012, Vol. 17 ›› Issue (5): 523-526.doi: 10.1007/s12204-012-1318-5

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Effect of Oxygen Content on Structural and Optical Properties of Single Cu2O Film by Reactive Magnetron Sputtering Method

LI Bin-bin1,2*(李斌斌), ZHU Jian-xun2 (朱建勋), CHEN Zhao-feng1 (陈照峰), SHEN Hong-lie1 (沈鸿烈), LUO Jian1 (罗建)   

  1. (1. College of Material Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, China; 2. Sinamo Science and Technology Company Limited, Nanjing 210013, China)
  • 出版日期:2012-10-30 发布日期:2012-11-16
  • 通讯作者: LI Bin-bin1,2*(李斌斌) E-mail:bbli@nuaa.edu.cn

Effect of Oxygen Content on Structural and Optical Properties of Single Cu2O Film by Reactive Magnetron Sputtering Method

LI Bin-bin1,2*(李斌斌), ZHU Jian-xun2 (朱建勋), CHEN Zhao-feng1 (陈照峰), SHEN Hong-lie1 (沈鸿烈), LUO Jian1 (罗建)   

  1. (1. College of Material Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, China; 2. Sinamo Science and Technology Company Limited, Nanjing 210013, China)
  • Online:2012-10-30 Published:2012-11-16
  • Contact: LI Bin-bin1,2*(李斌斌) E-mail:bbli@nuaa.edu.cn

摘要: Cuprous oxide (Cu2O) thin films have been deposited on glass substrate by reactive magnetron sputtering method using Cu target and argon oxygen gas atmosphere. Effect of oxygen flow rate on structural and optical properties of thin films has been discussed. The results of X-ray diffraction, ultraviolet-visible spectrophotometry and atomic force micrograph indicated that the condition window for single Cu2O phase was about 3.8 to 4.4 cm3/min, and the optimum oxygen flow rate was 4.2 cm3/min. The optical band gap Eg of Cu2O film was determined by using the data of transmittance versus wavelength, and slightly decreased from 2.46 to 2.40 eV with the increase of oxygen flow rate from 3.8 to 4.4 cm3/min. The Cu2O film formed at the oxygen flow rate of 4.2 cm3/min had an optical band gap of 2.43 eV.

关键词: cuprous oxide, reactive magnetron sputtering, oxygen flow rate

Abstract: Cuprous oxide (Cu2O) thin films have been deposited on glass substrate by reactive magnetron sputtering method using Cu target and argon oxygen gas atmosphere. Effect of oxygen flow rate on structural and optical properties of thin films has been discussed. The results of X-ray diffraction, ultraviolet-visible spectrophotometry and atomic force micrograph indicated that the condition window for single Cu2O phase was about 3.8 to 4.4 cm3/min, and the optimum oxygen flow rate was 4.2 cm3/min. The optical band gap Eg of Cu2O film was determined by using the data of transmittance versus wavelength, and slightly decreased from 2.46 to 2.40 eV with the increase of oxygen flow rate from 3.8 to 4.4 cm3/min. The Cu2O film formed at the oxygen flow rate of 4.2 cm3/min had an optical band gap of 2.43 eV.

Key words: cuprous oxide, reactive magnetron sputtering, oxygen flow rate

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