表面活性剂对可食性葛根淀粉膜性能的影响

上海交通大学学报（自然版） ›› 2012, Vol. 46 ›› Issue (05): 813-818.

表面活性剂对可食性葛根淀粉膜性能的影响

钟宇a,b,李云飞b,c

（上海交通大学a. 制冷与低温工程研究所； b. 食品科学与工程系；c. 陆伯勋食品安全研究中心，上海 200240）

收稿日期:2011-03-23 出版日期:2012-05-28 发布日期:2012-05-28
基金资助:
国家科技攻关计划重点项目（2008BAD91B02）

Effects of Surfactants on the Properties of Kudzu (Pueraria Lobata) Starch Films

ZHONG Yu-a, b , LI Yun-Fei-b, c

(a.Institute of Refrigeration and Cryogenic Engineering; b.Department of Food Science and Technology; c.Bor S. Luh Food Safety Research Center, Shanghai Jiaotong University, Shanghai 200240，China)

Received:2011-03-23 Online:2012-05-28 Published:2012-05-28

摘要/Abstract

摘要： 以葛根淀粉为基材，丙三醇为增塑剂，吐温20和司盘80为表面活性剂，采用流延法制备可食性葛根淀粉膜，并考察表面活性剂对葛根淀粉膜液及膜的结构与力学性能的影响.结果表明：2种表面活性剂均能够有效降低膜液的表面张力，可与葛根淀粉发生络合反应而形成单螺旋V型结晶，降低淀粉膜的拉伸强度、提高其断裂伸长率；吐温20可以增强淀粉膜液在玻璃及石蜡基材上的润湿性，使淀粉膜更加平整光滑，提高了淀粉膜的水溶性；司盘80可以增加膜的表面粗糙度，但降低了其透湿性；相比单一表面活性剂，混合表面活性剂的加入未能有效改善淀粉膜的力学性能.

关键词: 可食性包装膜, 葛根淀粉, 表面活性剂, 力学性能

Abstract: An edible film based on kudzu starch was prepared and the effect of the surfactant on physical and mechanical properties of the films was evaluated. For the film, glycerol as the plasticizer was added in the solution, besides tween 20 and span 80 were used as surfactants. It was found that each surfactant decreases surface tension of the filmforming solution, promotes the formation of V-type crystal in the film, decreases the mechanical strength and increases the flexibility of the film. Tween 20 improves the wettability of film-forming solution on both glass and paraffin wax substrates, smoothes the surface of the film and increases the film’s solubility. The film containing only tween 20 is rougher but has lower hygroscopicity than other films. Blendedsurfactant does not effectively improve the properties of the film as regarding the film containing single surfactant.

Key words: edible film, kudzu starch, surfactant, mechanical properties

中图分类号:

TS 236

钟宇a, b, 李云飞b, c. 表面活性剂对可食性葛根淀粉膜性能的影响[J]. 上海交通大学学报（自然版）, 2012, 46(05): 813-818.

ZHONG Yu-a, b , LI Yun-Fei-b, c . Effects of Surfactants on the Properties of Kudzu (Pueraria Lobata) Starch Films[J]. Journal of Shanghai Jiaotong University, 2012, 46(05): 813-818.

参考文献

［1］Pereda M, Aranguren M I, Marcovich N E. Water vapor absorption and permeability of films based on chitosan and sodium caseinate ［J］. Journal of Applied Polymer Science, 2009, 111 (6): 27772784.

［2］Avérous L, Fringant C, Moro L. Starchbased biodegradable materials suitable for thermoforming packaging ［J］. Starch/Staerke, 2001, 53 (8): 368371.

［3］程杰顺. 葛粉冲溶特性的研究［D］.合肥：合肥工业大学生物与食品工程学院, 2003.

［4］Zhong G, Chen Z D, We Y M. Physicochemical properties of lotus (Nelumbo nucifera Gaertn.) and kudzu (pueraria hirsute matsum.) starches ［J］. International Journal of Food Science and Technology, 2007, 42 (12): 14491455.

［5］杜先锋, 许时婴, 王璋. NaCl和糖对葛根淀粉糊化特性的影响［J］. 食品科学, 2002 (7): 3436.

DU Xianfeng, XU Shiying, WANG Zhang. Effects of NaCl and sugar on the gelatinization behavior of kuzu starch ［J］. Food Science, 2002 (7): 3436.

［6］黄德民, 宋成满. 乳化剂与面粉中大分子物质的相互作用及其应用［J］. 冷饮与速冻食品工业, 2005 (3): 2225,30.

HUANG Demin, SONG Chengman. Studies on the interaction betwemulsifier and flour components［J］. Beverage and Fast Frozen Food Industry, 2005 (3): 2225,30.

［7］Mondragón M, Arroyo K, RomeroGarcía J. Biocomposites of thermoplastic starch with surfactant［J］. Carbohydrate Polymers, 2008, 74 (2): 201208.

［8］Rodríguez M, Osés J, Ziani K, et al. Combined effect of plasticizers and surfactants on the physical properties of starch based edible films ［J］. Food Research International, 2006, 39 (8): 840846.

［9］Chen C H, Kuo W S, Lai L S. Effect of surfactants on water barrier and physical properties of tapioca starch/decolorized hsiantsao leaf gum films［J］. Food Hydrocolloids, 2009, 23 (3): 714721.

［10］黄祖强, 胡华宇, 童张法, 等. 玉米淀粉的机械活化及其流变特性研究［J］. 食品与机械, 2006 (1): 5052,65.

HUANG Zuqiang, HU Huayu, TONG Zhangfa, et al. Study on mechanical activation and rheological properties of maize starch ［J］. Food and Machinery, 2006 (1): 5052,65.

［11］林志荣,高群玉. 淀粉的湿热处理及其发展前景［J］. 粮食与饲料工业, 2005 (8): 2223.

［12］刘延奇, 秦令祥, 王晓静. 淀粉配体复合物的制备及结晶结构研究［J］. 食品与生物技术学报, 2010 (4): 488490.

LIU Yanqi, QIN Lingxiang, WANG Xiaojing. Preparation and crystal structure characteristics of starchligand complex ［J］. Journal of Food Science and Biotechnology, 2010 (4): 488490.

［13］Andreuccetti C, Carvalho R A, GaliciaGarcía T, et al. Effect of surfactants on the functional properties of gelatinbased edible films［J］. Journal of Food Engineering, 2011, 103 (2): 129136.

［14］Bourtoom T, Chinnan M S. Preparation and properties of rice starchchitosan blend biodegradable film ［J］. LWTFood Science and Technology, 2008, 41 (9): 16331641.

［15］Bertuzzi M A, Armada M, Gottifredi J C. Physicochemical characterization of starch based films ［J］. Journal of Food Engineering, 2007, 82 (1): 1725.

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