上海交通大学学报(自然版) ›› 2018, Vol. 52 ›› Issue (7): 853-859.doi: 10.16183/j.cnki.jsjtu.2018.07.014

• 学报(中文) • 上一篇    下一篇

辉光渗钽层的制备与烧蚀性能

万轶1,熊党生2,李建亮2   

  1. 1. 三江学院 机械与电气工程学院, 南京 210012; 2. 南京理工大学 材料科学与工程学院, 南京 210094
  • 出版日期:2018-07-28 发布日期:2018-07-28
  • 通讯作者: 万轶(1982-),女,江西省宜春市人,副教授,主要从事表面涂层制备及其摩擦磨损性能研究. 电话(Tel.):025-52897012; E-mail: wan2721@163.com.
  • 基金资助:
    江苏省自然科学基金项目(16KJB460014,BK20151487),国家自然科学基金项目(51101087)

Preparation of Glow Discharge Tantalum Coating and Its Ablation Properties

WAN Yi,XIONG Dangsheng,LI Jianliang   

  1. 1. Mechanical and Electrical Engineering School, Sanjiang University, Nanjing 210012, China; 2. School of Material Science and Engineering, Nanjing University of Science and Technology, Nanjing 210094, China
  • Online:2018-07-28 Published:2018-07-28

摘要: 为了研究渗钽层对合金表面烧蚀性能的影响,利用双层辉光等离子渗金属的方法,在34CrNi3Mo钢表面制备了渗钽层,研究了渗钽层的表面形貌、相结构、元素分布、硬度以及渗层与基体结合力的变化情况,并对其烧蚀性能和耐蚀性能进行试验研究.结果表明:渗钽层主要由体心立方α相钽组成,沉积层深度约为10μm,扩散层深度约5μm;渗钽层表面硬度约500HV0.2,与基体的结合力约65N;在相同的工况下,渗钽层的耐烧蚀性能优于基体,并能够阻止C、N与基体形成脆化层;随着脉冲烧蚀次数增加,烧蚀面积增大,但烧蚀深度均较浅;在高功率脉冲烧蚀工况下,渗钽层可以减轻金属的熔融和气化,从而提高了基体的耐烧蚀性能.

关键词: 金属钽, 烧蚀性能, 辉光等离子, 物相分析

Abstract: In order to study the effect of Ta layer on the corrosion resistance of the alloy surface, the diffused layer was prepared on the 34CrNi3Mo steel surface by double glow plasma infiltration. The surface morphology, phase structure, element distribution, hardness change and the adhesion between the infiltrated layer and the substrate were investigated. The ablation property and corrosion resistance of Ta layer were analyzed. The results show that Ta layer is mainly composed of BCC α-Ta composition with the deposition layer depth of about 10μm and diffusion layer depth of about 3μm. The surface layer hardness is about 500HV0.2 and the bonding strength is about 65N. Under the same working condition, the corrosion resistance of Ta layer is better than that of matrix, which can prevent the formation of the embrittlement between C/N and matrix. With the increasing numbers of pulse ablation, the ablation area increases but the ablation depth maintains shallow. In the case of the high power pulse ablation, the Ta layer can decrease the melting and vaporization process, and improve the ablation resistance of the matrix.

Key words: tantalum metal, ablation performance, glow discharge plasma, phase analysis

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