上海交通大学学报（英文版） ›› 2012, Vol. 17 ›› Issue (3): 257-262.doi: 10.1007/s12204-012-1264-2

• 论文 •    下一篇

Degradation Behavior of Epoxy Resins in Fibre Metal Laminates Under Thermal Conditions

ZHU Guo-liang 1,2 *(祝国梁), XIAO Yan-ping1,3 (肖艳萍), YANG Yong-xiang1,3,4 (杨永祥) WANG Jun2 (王俊), SUN Bao-de2 (孙宝德), BOOM Rob1   

  1. (1. Department of Materials Science and Engineering, Delft University of Technology, 2628 CD Delft, The Netherlands; 2. State Key Laboratory of Metal Matrix Composites, Shanghai Jiaotong University, Shanghai 200240, China; 3. Department of Metallurgical Engineering, Anhui University of Technology, Ma’anshan 243002, Anhui, China; 4. Institute of Ferrous Metallurgy, Northeastern University, Shenyang 110819, China)
  • 出版日期:2012-06-30 发布日期:2012-11-15
  • 通讯作者: ZHU Guo-liang1,2 (祝国梁) E-mail:glzhu1983@hotmail.com

Degradation Behavior of Epoxy Resins in Fibre Metal Laminates Under Thermal Conditions

ZHU Guo-liang1,2 * (祝国梁), XIAO Yan-ping1,3 (肖艳萍), YANG Yong-xiang1,3,4 (杨永祥) WANG Jun2 (王俊), SUN Bao-de2 (孙宝德), BOOM Rob1   

  1. (1. Department of Materials Science and Engineering, Delft University of Technology, 2628 CD Delft, The Netherlands; 2. State Key Laboratory of Metal Matrix Composites, Shanghai Jiaotong University, Shanghai 200240, China; 3. Department of Metallurgical Engineering, Anhui University of Technology, Ma’anshan 243002, Anhui, China; 4. Institute of Ferrous Metallurgy, Northeastern University, Shenyang 110819, China)
  • Online:2012-06-30 Published:2012-11-15
  • Contact: ZHU Guo-liang1,2 (祝国梁) E-mail:glzhu1983@hotmail.com

摘要： GLARE (glass fibre/epoxy reinforced aluminum laminate) is a member of the fiber metal laminate (FML) family, and is built up of alternating metal and fiber layers. About 500m2 GLARE is employed in each Airbus A380 because of the superior mechanical properties over the monolithic aluminum alloys, such as weight reduction, improved damage tolerance and higher ultimate tensile strength. Many tons of new GLARE scraps have been accumulated during the Airbus A380 manufacturing. Moreover, with the increasing plane orders of Airbus A380, more and more end-of-life (EOL) GLARE scrap will be generated after retire of planes within forty years. Thermal processing is a potential method for the material recycling and re-use from GLARE with the aim of environmental protection and economic benefits. The current study indicatdes that thermal delamination is a crucial pre-treatment step for the GLARE recycling. The decomposition behavior of the epoxy resins at elevated temperatures was investigated by using the simultaneous thermal analysis, thermogravimetry analysis (TGA) and differential scanning calorimetry (DSC). Based on the thermal analysis results, GLARE thermal delamination experiments at refined temperatures were carried out to optimize the treatment temperature and holding time.

关键词: fibre metal laminates, GLARE (glass fibre/epoxy reinforced aluminum laminate), recycling, decomposition kinetics, thermal degradation

Abstract: GLARE (glass fibre/epoxy reinforced aluminum laminate) is a member of the fiber metal laminate (FML) family, and is built up of alternating metal and fiber layers. About 500m2 GLARE is employed in each Airbus A380 because of the superior mechanical properties over the monolithic aluminum alloys, such as weight reduction, improved damage tolerance and higher ultimate tensile strength. Many tons of new GLARE scraps have been accumulated during the Airbus A380 manufacturing. Moreover, with the increasing plane orders of Airbus A380, more and more end-of-life (EOL) GLARE scrap will be generated after retire of planes within forty years. Thermal processing is a potential method for the material recycling and re-use from GLARE with the aim of environmental protection and economic benefits. The current study indicatdes that thermal delamination is a crucial pre-treatment step for the GLARE recycling. The decomposition behavior of the epoxy resins at elevated temperatures was investigated by using the simultaneous thermal analysis, thermogravimetry analysis (TGA) and differential scanning calorimetry (DSC). Based on the thermal analysis results, GLARE thermal delamination experiments at refined temperatures were carried out to optimize the treatment temperature and holding time.

Key words: fibre metal laminates, GLARE (glass fibre/epoxy reinforced aluminum laminate), recycling, decomposition kinetics, thermal degradation

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